(1Z)-1-(2,4-Dichlorophenyl)ethan-1-one semicarbazone

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(1Z)-1-(2,4-Dichloro­phen­yl)ethan-1-one semicarbazone

In the title compound, C(9)H(9)Cl(2)N(3)O, the semicarbazone group is approximately planar, with an r.m.s deviation from the mean plane of 0.011 (2) Å. The dihedral angle between the least-squares planes through the semicarbazone group and the benzene ring is 38.76 (9)°. The crystal structure is further stabilized by N-H⋯O and C-H⋯O hydrogen bonding.

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(E)-1-(4-Fluoro­phen­yl)ethan-1-one semicarbazone

In the title compound, C(9)H(10)FN(3)O, the semicarbazone group is nearly planar, with the maximum deviation of 0.044 (1) Å for one of the N atoms. The mean plane of semicarbazone group forms a dihedral angle of 30.94 (4)° with the benzene ring. The mol-ecules are linked into a supra-molecular chain by N-H⋯O hydrogen bonds formed along the c axis. The crystal structure is further stabilized by ...

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(E)-1-(4-Bromo­phen­yl)ethan-1-one semicarbazone

In the title compound, C(9)H(10)BrN(3)O, the hydrazone portion and aliphatic chain are essentially coplanar [maximum deviation 0.057 (15) Å] and the mean plane makes a dihedral angle of 70.9 (6)° with the benzene ring. The main feature of the crystal structure is the inter-molecular N-H⋯O hydrogen bond, which links mol-ecules into zigzag chains along the a axis. These chains are further stacked...

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(E)-1-Phenyl­ethanone semicarbazone

In the title compound, C(9)H(11)N(3)O, the benzene ring is disordered over two positions with refined occupancies of 0.922 (5) and 0.078 (5). The program PLATON [Spek (2009 ▶). Acta Cryst. D65, 148-155] recommends the solution in the space group C2/m with a = 7.3050 (3), b = 6.6745 (2), c = 18.3853 (6) Å and β = 96.986 (2)°. However, the large number of non-extinct reflections needed to be igno...

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(1Z)-1-(1-Benzo­furan-2-yl)ethanone oxime

The title compound, C10H9NO2, is almost planar (r.m.s. deviation for the non-H atoms = 0.027 Å) and the conformation across the C=N bond is syn. Further, the O atom of the benzo-furan ring is syn to the CH3 group in the side chain. In the crystal, mol-ecules are linked into C(3) chains propagating in [010] by O-H⋯N hydrogen bonds.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809029900